Effect of Plasticizers on Structural and Dielectric Behaviour of [PEO + (NH4)2C4H8(COO)2] Polymer Electrolyte | Zendy

Kamlesh Pandey | Zendy; Nidhi Asthana | Zendy; Mrigank Mauli Dwivedi | Zendy; S. K. Chaturvedi | Zendy

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Effect of Plasticizers on Structural and Dielectric Behaviour of [PEO + (NH₄)₂C₄H₈(COO)₂] Polymer Electrolyte

Author(s) -

Kamlesh Pandey,

Nidhi Asthana,

Mrigank Mauli Dwivedi,

S. K. Chaturvedi

Publication year - 2013

Publication title -

journal of polymers

Language(s) - English

Resource type - Journals

eISSN - 2356-7570

pISSN - 2314-6877

DOI - 10.1155/2013/752596

Subject(s) - plasticizer , electrolyte , materials science , polymer , dielectric spectroscopy , dielectric , conductivity , polarization (electrochemistry) , polyethylene oxide , oxide , relaxation (psychology) , chemical engineering , polymer chemistry , analytical chemistry (journal) , chemistry , composite material , electrochemistry , organic chemistry , electrode , metallurgy , psychology , social psychology , optoelectronics , engineering

Improvements in ion transport property of polyethylene-oxide- (PEO-) based polymer electrolytes have been investigated, using different types of plasticizers. The effects of single and coupled plasticizers [i.e., EC, (EC + PC), and (EC + PEG)] on structural and electrical behavior of pristine electrolyte were studied by XRD, SEM technique, and impedance spectroscopy. The electrical conductivity of the best plasticized system was found to be 4 × 10−6 S/cm. Argand plots show dispersive nature of relaxation time or inhomogeneous space charge polarization of plasticized polymer electrolyte

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