Synthesis of CIS Nanoink and Its Absorber Layer without Selenization
Author(s) -
Manoj Kumar,
Raghunandan Seelaboyina,
Kshitij Taneja,
Alekhya Venkata Madiraju,
Anup Kumar Keshri,
Sarang Mahajan,
K. Singh
Publication year - 2013
Publication title -
conference papers in energy
Language(s) - English
Resource type - Journals
eISSN - 2314-582X
pISSN - 2314-4009
DOI - 10.1155/2013/739532
Subject(s) - thin film , materials science , crystallinity , chalcopyrite , dispersant , layer (electronics) , band gap , chemical engineering , absorption (acoustics) , stoichiometry , analytical chemistry (journal) , nanotechnology , composite material , optoelectronics , optics , metallurgy , copper , organic chemistry , dispersion (optics) , chemistry , physics , engineering
Highly crystalline CIS nanoink was synthesized using highly efficient microwave route. Thin films of CIS were fabricated using the developed ink by drop casting method. XRD pattern of CIS thin films indicates that a chalcopyrite phase with good crystallinity can be obtained using developed ink and that the composition of precursor ink can be transferred directly to the thin film without change in the stoichiometry. The developed ink alleviates the need of organic binders/dispersant and high temperature selenization using highly toxic H2Se gas (or Na2Se as a Se source) after deposition of thin film absorber layer. UV-VIS-NIR absorption analysis indicates that CIS thin film has a band gap of around 1.18 eV.
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