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Nanostructured TiO2 Doped with Nb as a Novel Support for PEMFC
Author(s) -
Edgar Valenzuela,
Víctor H. Ramos-Sánchez,
Alejandro A. Lambert-Arista,
O. Savadogo
Publication year - 2013
Publication title -
journal of materials
Language(s) - English
Resource type - Journals
eISSN - 2314-4874
pISSN - 2314-4866
DOI - 10.1155/2013/706513
Subject(s) - proton exchange membrane fuel cell , materials science , catalysis , durability , oxide , dispersion (optics) , carbon fibers , catalyst support , electrochemistry , chemical engineering , doping , conductivity , metal , nanotechnology , composite material , metallurgy , chemistry , electrode , composite number , physics , optoelectronics , optics , engineering , biochemistry
Nowadays, one of the major issues of the PEMFC concerns the durability. Historically, carbon has been used as a catalyst support in PEMFC; nevertheless, under the environmental conditions of the cell, the carbon is oxidized, leaving the catalyst unsupported. In order to increase the stability and durability of the catalyst in the PEMFC, a novel nanostructured metallic oxide support is proposed. In this work, TiO2 was doped with Nb to obtain a material that combines chemical stability, high surface area, and an adequate electronic conductivity in order to be a successful catalyst support candidate for long-term PEMFC applications. The TiO2-Nb nanostructured catalyst support was physically and electrochemically characterized. According to the results, the TiO2-Nb offers high surface area and good particle dispersion; also, the electrochemical activity and stability of the support were evaluated under high potential conditions, where the TiO2-Nb proved to be much more stable than carbon

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