Studies on AC Electrical Conductivity of CdCl2Doped PVA Polymer Electrolyte | Zendy

M. B. Nanda Prakash | Zendy; A. Manjunath | Zendy; R. Somashekar | Zendy

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Studies on AC Electrical Conductivity of CdCl₂Doped PVA Polymer Electrolyte

Author(s) -

M. B. Nanda Prakash,

A. Manjunath,

R. Somashekar

Publication year - 2013

Publication title -

advances in condensed matter physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.314

H-Index - 26

eISSN - 1687-8124

pISSN - 1687-8108

DOI - 10.1155/2013/690629

Subject(s) - crystallite , electrolyte , materials science , conductivity , polymer , ionic conductivity , doping , ionic bonding , analytical chemistry (journal) , solvent , chemical engineering , composite material , ion , chemistry , chromatography , organic chemistry , electrode , metallurgy , engineering , optoelectronics

PVA-based polymer electrolytes were prepd. with various concns. of CdCl2 using solvent casting method. Prepd. polymer films were investigated using line profile anal. employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with increase in CdCl2. AC cond. in these polymer increases films first and then decreases. These observations are in agreement with XRD results. The highest ionic cond. of 1.68E-08 Scm-1 was obsd. in 4% of CdCl2 in PVA polymer blend. Crystallite ellipsoids for different concns. of CdCl2 are computed here using whole pattern powder fitting (WPPF) indicating that crystallite area decreases with increase in the ionic cond. [on SciFinder(R)

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