Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki‐Heck Reaction of Aryl Bromides | Zendy

Siti Kamilah Che Soh | Zendy; Mustaffa Shamsuddin | Zendy

Open Access

Tetradentate N₂O₂ Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki‐Heck Reaction of Aryl Bromides

Author(s) -

Siti Kamilah Che Soh,

Mustaffa Shamsuddin

Publication year - 2012

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.436

H-Index - 50

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2013/632315

Subject(s) - chemistry , palladium , catalysis , aryl , propane , diamine , phosphine , methyl acrylate , chelation , polymer chemistry , heck reaction , medicinal chemistry , organic chemistry , copolymer , alkyl , polymer

Four air and moisture-stable palladium(II)-Schiff base complexes, N,N′-bis(α-methylsalicylidene)propane-1,3-diamine palladium(II) (2a), N,N′-bis(4-methyl-α-methylsalicylidene)propane-1,3-diamine palladium(II) (2b), N,N′-bis(3,5-di-tert-butylsalicylidene)propane-1,3-diamine palladium(II) (2c), and N,N′-bis(4-methoxy-salicylidene)propane-1,3-diamine palladium(II) (2d), have been successfully synthesised and characterised by CHN elemental analyses and conventional spectroscopic methods. These complexes were investigated as catalysts in the phosphine-free Mizoroki-Heck cross-coupling reactions of aryl bromides with methyl acrylate

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