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Hydrothermal Synthesis of Pt-, Fe-, and Zn-dopedSnO2Nanospheres and Carbon Monoxide Sensing Properties
Author(s) -
Weigen Chen,
Qu Zhou,
Shudi Peng
Publication year - 2013
Publication title -
advances in materials science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 42
eISSN - 1687-8442
pISSN - 1687-8434
DOI - 10.1155/2013/578460
Subject(s) - materials science , hydrothermal circulation , dopant , doping , carbon monoxide , analytical chemistry (journal) , hydrothermal synthesis , spectroscopy , nanotechnology , chemical engineering , physics , optoelectronics , organic chemistry , catalysis , chemistry , quantum mechanics , engineering
Pure and M-doped (M = Pt, Fe, and Zn) SnO2 nanospheres were successfully synthesized via a simple and facile hydrothermal method and characterized by X-ray powder diffraction, field-emission scanning electron microscopy, and energy dispersive spectroscopy. Chemical gas sensors were fabricated based on the as-synthesized nanostructures, and carbon monoxide sensing properties were systematically measured. Compared to pure, Fe-, and Zn-doped SnO2 nanospheres, the Pt-doped SnO2 nanospheres sensor exhibits higher sensitivity, lower operating temperature, more rapid response and recovery, better stability, and excellent selectivity. In addition, a theoretical study based on the first principles calculation was conducted. All results demonstrate the potential of Pt dopant for improving the gas sensing properties of SnO2-based sensors to carbon monoxide

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