CuO-CeO 2 Nanocomposite: An Efficient Recyclable Catalyst for the Synthesis of Aryl-14H-dibenzo[a-j]xanthenes
Author(s) -
Jalal Albadi,
Abdolhossein Razeghi,
Hossein Abbaszadeh,
Azam Mansournezhad
Publication year - 2013
Publication title -
journal of nanoparticles
Language(s) - English
Resource type - Journals
eISSN - 2314-4858
pISSN - 2314-484X
DOI - 10.1155/2013/546194
Subject(s) - coprecipitation , materials science , catalysis , amorphous solid , nanoparticle , nanocomposite , nanoclusters , bet theory , chemical engineering , nuclear chemistry , analytical chemistry (journal) , nanotechnology , crystallography , organic chemistry , chemistry , engineering
CuO-CeO2 nanocomposite is reported as a highly efficient recyclable catalyst that is applied for the synthesis of Aryl-14H-dibenzo[a-j]xanthenes under solvent-free conditions. The catalyst was synthesized by coprecipitation method and characterized by X-ray powder diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), and energy dispersive spectroscopy (EDS) analysis. The copper nanoparticles are dispersed as fine and amorphous phases on the surface of ceria and made nanoclusters with average size of about 33 nm. This catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any losing of its efficiency. This procedure provides several advantages such as simple workup, mild reaction conditions, short reaction times, and high yields of the products
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