English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

Reaction of Ce with p-tert-butylcalix[n]arene (n = 4, 6, 8) yields purple crystalline complexes structurally as [Ce(p-tertbutylcalix[4]arene-3H) 2 (NO 3 )(DMF) x ](2 − x)DMF (1), [Ce(p-tert-butylcalix[6]arene-4H) 2 (NO 3 )(DMF) x ](3 − x)DMF (2), and [Ce(p-tert-butylcalix[8]arene-7H) 2 (NO 3 )(DMF) 6 ] (3), where DMF = N,N-dimethylformamide. The properties and coordination characteristics of the three calixarene complexes were determined by elemental analyses, electronic absorption, X-ray absorption spectroscopy (EXAFS), TG-DTA, FT-IR, SEM, and H-NMR spectroscopy.The effect of various organic solvents on complexes 1, 2, and 3 has been discussed based on results from electronic absorption spectra.The polar protic solvents showed the most significant molar extinction coefficients in comparison with those of nonpolar and polar aprotic solvents. The Ce ions in the complexes are proved to combine with the ligand phenolic groups, oxygen atoms of DMF molecules, and/or OH ions.

Synthesis and Characterization of Trivalent Cerium Complexes of p-tert-Butylcalix[4,6,8]Arenes: Effect of Organic Solvents