Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound | Zendy

A. Oueslati | Zendy; I. Chaabane | Zendy; Karim Adil | Zendy; F. Hlel | Zendy

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Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound

Author(s) -

A. Oueslati,

I. Chaabane,

Karim Adil,

F. Hlel

Publication year - 2012

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.436

H-Index - 50

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2013/435462

Subject(s) - chemistry , characterization (materials science) , infrared , infrared spectroscopy , nanotechnology , environmental chemistry , organic chemistry , optics , physics , materials science

New inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (2). Besides, its structure was solved using 84860 independent reflections leading to . Electrical properties of the material were studied using impedance spectroscopic technique at different temperatures in the frequency range of 209 Hz to 5 MHz. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature-dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound

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