Synthesis and Crystal Structure of trans-Diiodobis(piperidine-1-carbonitrile)platinum(II) | Zendy

Aleksey L. Mindich | Zendy; Matti Haukka | Zendy; Nadezhda A. Bokach | Zendy

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Synthesis and Crystal Structure of trans-Diiodobis(piperidine-1-carbonitrile)platinum(II)

Author(s) -

Aleksey L. Mindich,

Matti Haukka,

Nadezhda A. Bokach

Publication year - 2013

Publication title -

journal of crystallography

Language(s) - English

Resource type - Journals

eISSN - 2356-7317

pISSN - 2314-5994

DOI - 10.1155/2013/312310

Subject(s) - piperidine , platinum , chemistry , iodide , crystal structure , halide , ligand (biochemistry) , crystallography , methanol , methyl iodide , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , receptor

Treatment of dichlorobis(piperidine-1-carbonitrile)platinum(II) with potassium iodide in water/methanol mixture results in the halide ligand exchange giving novel trans-diiodobis(piperidine-1-carbonitrile)platinum(II) complex. The reaction proceeds under mild conditions (20°C, 40 min) giving trans-[PtI2(NCNC5H10)2] in 70% isolated yield. The iodide complex was characterized by IR, 1H and 13C NMR spectroscopies, and high resolution ESI-MS, and its structure was determined by a single crystal X-ray diffraction.

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