Electrochemical Response for Spherical and Rod Shaped WO3 Nanoparticles
Author(s) -
Sangeeta Adhikari,
Debasish Sarkar
Publication year - 2013
Publication title -
isrn nanotechnology
Language(s) - English
Resource type - Journals
eISSN - 2090-6072
pISSN - 2090-6064
DOI - 10.1155/2013/279398
Subject(s) - tungsten trioxide , materials science , electrode , nanoparticle , monoclinic crystal system , tungsten , electrochemistry , reagent , coating , nanotechnology , chemical engineering , band gap , phase (matter) , optoelectronics , crystal structure , crystallography , chemistry , organic chemistry , metallurgy , engineering
A rapid and new technique describes synthesis technique of spherical and rod shaped tungsten trioxide (WO3) nanoparticles with similar band gap at visible wavelength. Acid catalyzed exothermic reaction and structure directing reagent follows the formation of two different morphologies and monoclinic WO3 phase. Rod shaped WO3 nanoparticle coated ITO glass electrode exhibits high current density at identical low voltage and scan rate due to its better adherence and coating uniformity in comparison with spherical nanoparticles. WO3-ITO electrode alters to blue tungsten bronze in color at low voltage, and further the color restores after removing the same applied voltage.
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