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Condensation Polymers of Terephthalic Acid and 1,4-Diaminobutane and Their Schiff Base Complexes
Author(s) -
Sandeep Rai,
Anjali Bajpai,
Snehal Lokhandwala
Publication year - 2013
Publication title -
journal of polymers
Language(s) - English
Resource type - Journals
eISSN - 2356-7570
pISSN - 2314-6877
DOI - 10.1155/2013/278576
Subject(s) - salicylaldehyde , terephthalic acid , schiff base , thermogravimetric analysis , polymer chemistry , chemistry , polyamide , condensation , ligand (biochemistry) , elemental analysis , organic chemistry , polyester , biochemistry , physics , receptor , thermodynamics
Amino-terminated oligomeric poly(tetramethylene terephthalamide) (PTTA) was prepared by condensation of terephthalic acid and 1,4-diaminobutane using phosphorylation technique. Schiff base complexes of this polyamide were synthesized with salicylaldehyde and 2-hydroxy-1-naphthaldehyde complexes of Co(II), Ni(II), and Cu(II). The polyamide as well as Schiff base complexes were characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. Thermal stabilities of ligand and its various complexes were compared by thermogravimetric analysis

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