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The ready accessibility of ( R )-  α  -aminoadipic acid by enzymatic cleavage of cephalosporin C (CephC) in the production of 7-aminocephalosporanic acid (7-ACA) on a large scale makes it a favorable chiral pool building block for the synthesis of unusual amino acids. A route for the synthesis of C-5-alkenyl and C-6-alkylidene derivatives of ( R )-pipecolic acid is described which utilizes ( R )-  α  -aminoadipic acid as the enantiomerically pure starting material. Moreover, the synthesis of azido and triazolyl derivatives of ( R )-  α  -aminoadipic acid is reported.

(R)-α-Aminoadipic Acid: A Versatile Precursor for the Synthesis of D-Amino Acids