Hybrid Layered Crystal Comprising Polyoxometalate and Surfactant Synthesized from Reduced Mo‐Blue Species | Zendy

Keisuke Mikurube | Zendy; Kimiko Hasegawa | Zendy; Haruo Naruke | Zendy; Takeru Ito | Zendy

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Hybrid Layered Crystal Comprising Polyoxometalate and Surfactant Synthesized from Reduced Mo‐Blue Species

Author(s) -

Keisuke Mikurube,

Kimiko Hasegawa,

Haruo Naruke,

Takeru Ito

Publication year - 2013

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.436

H-Index - 50

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2013/208075

Subject(s) - polyoxometalate , chemistry , crystallography , molecule , pyridine , crystallization , crystal structure , crystal (programming language) , hybrid material , molybdenum , stereochemistry , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , computer science , programming language

A hybrid layered crystal containing polyoxomolybdate was successfully synthesized from reduced Mo-blue species as starting material. The hybrid crystal, [C5H5N(C16H33)]2[β-H2Mo8O26]·2C2H5OH (C16py-H2Mo8), was obtained as a single phase by the gradual oxidation of hexadecylpyridinium-Mo-blue (C16py-Mo-blue) hybrid. The X-ray structure analysis revealed that C16py-H2Mo8 comprised β-type octamolybdate anion with two protons (β-H2Mo8). The β-H2Mo8 anions and ethanol molecules of crystallization formed two-dimensional anionic layers. The pyridine rings of C16py did not attend to form the two-dimensional inorganic layers, and the interdigitated C16py bilayers were sandwiched by the β-H2Mo8 anionic layers with periodicity of 18.2 Å. These C16py-H2Mo8 hybrid layered crystals possibly work as a new class of proton conductor

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