Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands | Zendy

Saeideh Hosseini | Zendy; Farzin Marandi | Zendy; Ertan Şahi̇n | Zendy; Seyid Javad Musevi | Zendy

Open Access

Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands

Author(s) -

Saeideh Hosseini,

Farzin Marandi,

Ertan Şahi̇n,

Seyid Javad Musevi

Publication year - 2012

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.436

H-Index - 50

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2013/159125

Subject(s) - chemistry , lone pair , supramolecular chemistry , crystallography , coordination number , elemental analysis , coordination complex , crystal structure , coordination sphere , ion , stereochemistry , inorganic chemistry , molecule , metal , organic chemistry

A new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure

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