Determination of Thiocyanate by Kinetic Spectrophotometric Flow Injection Analysis
Author(s) -
Mohsen Keyvanfard,
Khadijeh Alizad,
Parinaz Elahian
Publication year - 2012
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.436
H-Index - 50
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2013/147364
Subject(s) - chemistry , thiocyanate , flow injection analysis , kinetic energy , stopped flow , chromatography , flow (mathematics) , kinetics , inorganic chemistry , reaction rate constant , mechanics , detection limit , physics , quantum mechanics
A simple and rapid flow injection spectrophotometric method has been developed for the determination of amount of thiocyanate in wastewaters and well water samples. It is based on the reaction of thiocyanate in hydrochloric acid with janus green and bromate. Reaction was monitored spectrophotometrically by measuring janus green absorbance at max=554 nm. The calibration graph was linear over the range 0.02–1.0 μg mL−1 and the detection limit was 0.016 μg mL−1 (/=3). The throughput was 25 samples per hour.
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