Interesting Behavior ofPachycormus discolorLeaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1 M HCl: A Preliminary Study
Author(s) -
Ramses García Inzunza,
Benjamín Valdez,
Rita Kharshan,
Alla Furman,
Μ. Schorr
Publication year - 2011
Publication title -
international journal of corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.312
H-Index - 18
eISSN - 1687-9333
pISSN - 1687-9325
DOI - 10.1155/2012/980654
Subject(s) - adsorption , corrosion , carbon steel , ethanol , gravimetric analysis , langmuir adsorption model , nuclear chemistry , polarization (electrochemistry) , fourier transform infrared spectroscopy , electrochemistry , materials science , chemistry , inorganic chemistry , metallurgy , chemical engineering , organic chemistry , electrode , engineering
The purpose of this paper is to evaluate the inhibitive action of an ethanol extract from the leaves of Pachycormus discolor (EEPD) on the corrosion of carbon steel in 1 M HCl at different temperatures; gravimetric method and electrochemical tests were conducted. Potentiodynamic polarization was used at room temperature and resistance polarization at different temperatures. Thermodynamic adsorption parameters are shown in order to demonstrate the spontaneous adsorption. The inhibition of EEPD was performed via adsorption of the extract species on the carbon steel surface. The ethanol extract obeys Langmuir adsorption isotherm. Potentiodynamic polarization results indicate that the ethanol extract acts as a mixed type inhibitor. The results revealed that the inhibition efficiency (IE) of EEPD increases (when the concentration is increased). Phytochemical and FTIR analyses are also presented in this work. It was found that the IE increases with the temperature in a 2.0% v/v solution which showed 94.52% IE at 25∘C and 97.89% at 75∘C
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