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Performance Degradation of Dye-Sensitized Solar Cells Induced by Electrolytes
Author(s) -
RuYuan Yang,
Huang-Yu Chen,
FuDer Lai
Publication year - 2012
Publication title -
advances in materials science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 42
eISSN - 1687-8442
pISSN - 1687-8434
DOI - 10.1155/2012/902146
Subject(s) - dye sensitized solar cell , electrolyte , materials science , short circuit , degradation (telecommunications) , equivalent series resistance , open circuit voltage , solar cell , current density , optoelectronics , electrode , analytical chemistry (journal) , voltage , electrical engineering , chemistry , environmental chemistry , physics , quantum mechanics , engineering
We investigated the change of the electric characteristics in dye-sensitized solar cell (DSSC) when the electrolyte has been injected and measured initially and lately for a period of time. It was found that the short-circuit current density decreased from 9.799 mA/cm2 to 7.056 mA/cm2 and the fill factor increased from 0.406 to 0.559 when the cell had stood for an hour, while the open-circuit photovoltage did not change due to fixed difference between the Fermi level of TiO2 and the oxidation-reduction potential of electrolyte. The results can be explained by using the variation of the series resistance in the equivalent circuit of the DSSC.

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