Open AccessA Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
Author(s) -
Lihong Huang,
JiDong Lou,
Changhe Zhang,
Fang Lin,
XiaoNan Zou
Publication year - 2011
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2012/826527
Subject(s) - potassium dichromate , dimethylformamide , homogeneous , potassium , chemistry , organic chemistry , nuclear chemistry , mathematics , combinatorics , solvent
Oxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to using a polar aprotic solvent
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