Open AccessOxidative Carbonylation of 2-Propyn-1-ol and 2-Methyl-3-butyn-2-ol in an Oscillatory Mode
Author(s) -
Sergey N. Gorodsky
Publication year - 2012
Publication title -
organic chemistry international
Language(s) - English
Resource type - Journals
eISSN - 2090-2018
pISSN - 2090-200X
DOI - 10.1155/2012/819190
Subject(s) - carbonylation , homogeneous , chemistry , oxidative phosphorylation , mode (computer interface) , medicinal chemistry , catalysis , organic chemistry , physics , thermodynamics , carbon monoxide , computer science , biochemistry , operating system
The oscillatory modes of oxidative carbonylation reaction of two new substrates—2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI2-KI-CO-O2-CH3OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offered
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