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Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method
Author(s) -
Toshifumi Satoh
Publication year - 2012
Publication title -
international journal of polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.399
H-Index - 33
eISSN - 1687-9430
pISSN - 1687-9422
DOI - 10.1155/2012/816163
Subject(s) - monomer , branching (polymer chemistry) , polymer , macromolecule , polymer chemistry , materials science , polymerization , chemical engineering , chemistry , composite material , biochemistry , engineering
This paper details the synthesis of a well-defined hyperbranched polymer using a slow monomer addition method. The polymerization under slow monomer addition conditions results in a very low monomer concentration actually present in the reaction mixture, and the exclusive reaction of the monomer with the growing polyfunctional macromolecules occurs, resulting in a high molecular weight and a high degree of branching value. Thus, the slow monomer addition is a versatile and preferential method for the controlled synthesis of a well-defined hyperbranched polymer with both a high molecular weight and a high degree of branching value

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