Synthesis, Characterization and Antimicrobial Studies of a New Mannich Base N‐[Morpholino(phenyl)methyl]acetamide and Its Cobalt(II), Nickel(II) and Copper(II) Metal Complexes | Zendy

L. Muruganandam | Zendy; K. Krishnakumar | Zendy

Open Access

Synthesis, Characterization and Antimicrobial Studies of a New Mannich Base N‐[Morpholino(phenyl)methyl]acetamide and Its Cobalt(II), Nickel(II) and Copper(II) Metal Complexes

Author(s) -

L. Muruganandam,

K. Krishnakumar

Publication year - 2011

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2012/767941

Subject(s) - chemistry , acetamide , tetracoordinate , cobalt , hexacoordinate , mannich base , morpholine , nickel , denticity , moiety , copper , ligand (biochemistry) , polymer chemistry , stereochemistry , inorganic chemistry , metal , medicinal chemistry , organic chemistry , biochemistry , computer graphics (images) , receptor , silicon , computer science , planar

A new Mannich base N-[morpholino(phenyl)methyl]acetamide (MBA), was synthesized and characterized by spectral studies. Chelates of MBA with cobalt(II), nickel(II) and copper(II) ions were prepared and characterized by elemental analyses, IR and UV spectral studies. MBA was found to act as a bidentate ligand, bonding through the carbonyl oxygen of acetamide group and CNC nitrogen of morpholine moiety in all the complexes. Based on the magnetic moment values and UV-Visible spectral data, tetracoordinate geometry for nitrato complexes and hexacoordinate geometry for sulphato complexes were assigned. The antimicrobial studies show that the Co(II) nitrato complex is more active than the other complexes

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research