Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids | Zendy

Satish C. Dixit | Zendy; Rohit K. Singh | Zendy

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Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids

Author(s) -

Satish C. Dixit,

Rohit K. Singh

Publication year - 2011

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2012/631391

Subject(s) - zirconium , cyclopentadienyl complex , chemistry , pyridine , medicinal chemistry , stoichiometry , nuclear chemistry , inorganic chemistry , organic chemistry , catalysis

Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data

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