Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
Author(s) -
Jaehyoung Park,
Kichang Jung,
Ari Lee,
Hyojung Bae,
Daehwa Mun,
JunSeok Ha,
Young-Bu Mun,
E. M. Han,
Hang-Ju Ko
Publication year - 2012
Publication title -
international journal of photoenergy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.426
H-Index - 51
eISSN - 1687-529X
pISSN - 1110-662X
DOI - 10.1155/2012/614320
Subject(s) - materials science , band gap , layer (electronics) , thin film , analytical chemistry (journal) , optoelectronics , chemistry , nanotechnology , chromatography
Organic/inorganic hybrid solar cells were fabricated incorporating aluminum-doped zinc oxide (AZO) thin films of varying optical band gap in AZO/poly(2-methoxy-5-(2′-ethyl-hexyloxy)-p-phenylene vinylene) structures. The band gaps were controlled by varying the flow rates of Ar and O2 used to deposit the AZO. Devices with CdS buffer layer were also fabricated for improved efficiency. The effects of AZO optical band gap were assessed by testing the I–V characteristics of devices with structures of glass/ITO/AZO/MEH-PPV/Ag under AM1.5 illumination (100 mW/cm2). Efficiency was improved about 30 times by decreasing the AZO optical band gap, except in devices deposited without oxygen. A power conversion efficiency of 0.102% was obtained with the incorporation of a CdS buffer layer
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