Synthesis, Characterization, and Evaluation of Boron-Doped Iron Oxides for the Photocatalytic Degradation of Atrazine under Visible Light
Author(s) -
Shan Hu,
Guanglong Liu,
Duanwei Zhu,
Chao Chen,
Shuijiao Liao
Publication year - 2011
Publication title -
international journal of photoenergy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.426
H-Index - 51
eISSN - 1687-529X
pISSN - 1110-662X
DOI - 10.1155/2012/598713
Subject(s) - hematite , photocatalysis , materials science , doping , goethite , visible spectrum , boron , atrazine , degradation (telecommunications) , diffuse reflection , boron oxide , iron oxide , nuclear chemistry , inorganic chemistry , chemistry , oxide , catalysis , metallurgy , optics , organic chemistry , adsorption , optoelectronics , pesticide , computer science , biology , telecommunications , physics , agronomy
Photocatalytic degradation of atrazine by boron-doped iron oxides under visible light irradiation was investigated. In this work, boron-doped goethite and hematite were successfully prepared by sol-gel method with trimethylborate as boron precursor. The powders were characterized by XRD, UV-vis diffuse reflectance spectra, and porosimetry analysis. The results showed that boron doping could influence the crystal structure, enlarge the BET surface area, improve light absorption ability, and narrow their band-gap energy. The photocatalytic activity of B-doped iron oxides was evaluated in the degradation of atrazine under the visible light irradiation, and B-doped iron oxides showed higher atrazine degradation rate than that of pristine iron oxides. Particularly, B-doped goethite exhibited better photocatalytic activity than B-doped hematite
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