Synthesis and Characterization of Salicylate Derivatives of Dibutyl Sn(IV)-Ti(IV)-μ-Oxoisopropoxide
Author(s) -
Rajesh Kumar
Publication year - 2011
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2012/450821
Subject(s) - chemistry , molar ratio , condensation , elemental analysis , nuclear chemistry , methyl salicylate , derivative (finance) , ion , medicinal chemistry , organic chemistry , catalysis , ecology , physics , biology , financial economics , economics , thermodynamics
New Salicylate derivatives of organoheterobimetallic-μ-oxoisopropoxide [Bu2SnO2Ti2(OPri)6] have been synthesized by the thermal condensation of μ-oxoisopropoxide compound with different salicylates in different molar ratios (1:1-1:4) yielded the compounds of the type [Bu2SnO2Ti2(OPri)6-n(RSal)n] (where n is 1-4 and RSal = Salicylate anion) respectively. The μ-oxoisopropoxide derivative has been characterized by elemental, liberated isopropanol, and spectral analysis (IR, 1H, 13C, and 119Sn NMR)
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom