Stability Constants of Mixed Ligand Complexes of Transition Metal(II) ions with N-(2-hydroxybenzylidene)-2,3-dimethylaniline as Primary Ligand and N-(2-hydroxy-1-naphthylidene)-4-nitroaniline as Secondary Ligand
Author(s) -
A.K. Mapari,
Kiran Mangaonkar
Publication year - 2010
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2011/986907
Subject(s) - ligand (biochemistry) , chemistry , dimethylaniline , primary (astronomy) , ion , transition metal , photochemistry , organic chemistry , receptor , catalysis , physics , biochemistry , astronomy
Binary and ternary complexes of the type M-Y and M-X-Y [M=Co(II), Ni(II), Cu(II) and Zn(II); X=N-(2-hydroxybenzylidene)-2,3-dimethylaniline and Y = N-(2-hydroxy-1-naphthylidene)-4-nitroaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ=0.1 M (KCl) in 75:25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated
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