Oxidation of Methionine by Tripropylammonium Fluorochromate-A Kinetic and Mechanistic Study | Zendy

S. Sheik Mansoor | Zendy

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Oxidation of Methionine by Tripropylammonium Fluorochromate-A Kinetic and Mechanistic Study

Author(s) -

S. Sheik Mansoor

Publication year - 2010

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2011/945236

Subject(s) - acrylonitrile , chemistry , methionine , acetic acid , chloroacetic acid , aqueous solution , polymerization , kinetics , decomposition , organic chemistry , amino acid , biochemistry , polymer , physics , quantum mechanics , copolymer

The kinetics of oxidation of methionine (Met) by tripropylammonium fluorochromate (TriPAFC) has been studied in the presence of chloroacetic acid in aqueous acetic acid medium. The reaction is first order with respect to methionine, TriPAFC and acid. The reaction rate has been determined at different temperatures and activation parameters calculated. With an increase in the amount of acetic acid in its aqueous mixture, the rate increases. The reaction does not induce polymerization of acrylonitrile. A suitable mechanism has been proposed

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