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The photocatalytic depolymerization of Dagang vacuum residue (DVR) wascarried out with  H2O2 overTiO2 in a photochemical reactor. Most of the organicmatter in DVR was converted into oxygen-containing organic compounds.The yields of carboxylic acids, oxalates, epoxy compounds, andhydroxyl compounds from DVR oxidation are 40.6%, 36.4%,17.86%, and 13.5%, respectively. In addition, the oxidationcauses significant decrease in viscosity and chromaticity of DVR. Therelated reaction mechanisms are discussed according to theexperimental results

international journal of photoenergy

Conversion of Dagang Vacuum Residue into Oxygen-Containing Organic Compounds by Photo-Oxidation with<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mtext>H</mml:mtext><mml:mn mathvariant="bold">2</mml:mn></mml:msub><mml:msub><mml:mtext>O</mml:mtext><mml:mn mathvariant="bold">2</mml:mn></mml:msub></mml:mrow></mml:math>over<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mrow><mml:mtext>TiO</mml:mtext></mml:mrow><mml:mn …

Conversion of Dagang Vacuum Residue into Oxygen-Containing Organic Compounds by Photo-Oxidation withH2O2overTiO