Structure and Properties of - Nanocomposite Films for Biomedical Applications
Author(s) -
Lin Zhang,
Zhihua Sun,
Fengmei Yu,
Hongbin Chen
Publication year - 2011
Publication title -
bioinorganic chemistry and applications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.865
H-Index - 35
eISSN - 1565-3633
pISSN - 1687-479X
DOI - 10.1155/2011/853048
Subject(s) - x ray photoelectron spectroscopy , nanocomposite , doping , microstructure , band gap , scanning electron microscope , grain size , sputtering , spectroscopy , materials science , analytical chemistry (journal) , semiconductor , nanotechnology , thin film , chemical engineering , chemistry , optoelectronics , composite material , physics , chromatography , quantum mechanics , engineering
The hemocompatibility of La 2 O 3 -doped TiO 2 films with different concentration prepared by radio frequency (RF) sputtering was studied. The microstructures and blood compatibility of TiO 2 films were investigated by scan electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-visible optical absorption spectroscopy, respectively. With the increasing of the La 2 O 3 concentrations, the TiO 2 films become smooth, and the grain size becomes smaller. Meanwhile, the band gap of the samples increases from 2.85 to 3.3 eV with increasing of the La 2 O 3 content in TiO 2 films from 0 to 3.64%. La 2 O 3 -doped TiO 2 films exhibit n-type semiconductor properties due to the existence of Ti 2+ and Ti 3+ . The mechanism of hemocompatibility of TiO 2 film doped with La 2 O 3 was analyzed and discussed.
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