Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine | Zendy

Lotfali Saghatforoush | Zendy; Laura Valencia | Zendy; Firoozeh Chalabian | Zendy; S. Ghammamy | Zendy

Open Access

Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine

Author(s) -

Lotfali Saghatforoush,

Laura Valencia,

Firoozeh Chalabian,

S. Ghammamy

Publication year - 2011

Publication title -

bioinorganic chemistry and applications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.865

H-Index - 35

eISSN - 1565-3633

pISSN - 1687-479X

DOI - 10.1155/2011/803292

Subject(s) - terpyridine , chemistry , cadmium , ligand (biochemistry) , characterization (materials science) , combinatorial chemistry , crystallography , stereochemistry , nanotechnology , metal , organic chemistry , biochemistry , receptor , materials science

A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I) 2 ], has been synthesized and characterized by CHN elemental analysis, 1 H-NMR, 13 C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses show that the coordination number in complex is five with three terpyridine (Cltpy) N-donor atoms and two iodine atoms. The antibacterial activities of Cltpy and its Cd(II) complex are tested against different bacteria.

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