Inhibition Effect of 1-Butyl-4-Methylpyridinium Tetrafluoroborate on the Corrosion of Copper in Phosphate Solutions | Zendy

M. Scendo | Zendy; J. Uznanska | Zendy

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Inhibition Effect of 1-Butyl-4-Methylpyridinium Tetrafluoroborate on the Corrosion of Copper in Phosphate Solutions

Author(s) -

M. Scendo,

J. Uznanska

Publication year - 2011

Publication title -

international journal of corrosion

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.312

H-Index - 18

eISSN - 1687-9333

pISSN - 1687-9325

DOI - 10.1155/2011/761418

Subject(s) - corrosion , copper , adsorption , langmuir adsorption model , tetrafluoroborate , scanning electron microscope , inorganic chemistry , electrochemistry , ionic liquid , polarization (electrochemistry) , materials science , phosphate , nuclear chemistry , chemistry , metallurgy , organic chemistry , composite material , electrode , catalysis

The influence of the concentration of 1-Butyl-4-methylpyridinium tetrafluoroborate (4MBPBF 4) as ionic liquid (IL) on the corrosion of copper in 0.5 M P O 4 3 − solutions of pH 2 and 4 was studied. The research involved electrochemical polarization method, and scanning electron microscopy (SEM) technique. The results obtained showed that the inhibition efficiency of corrosion of copper increases with an increase in the concentration of 4MBPBF 4 but decreases with increasing temperature. The thermodynamic functions of corrosion analysis and adsorptive behavior of 4MBPBF 4 were carried out. During the test, the adsorption of the inhibitor on the copper surface in the phosphate solutions was found to obey the Langmuir adsorption isotherm and had a physical mechanism.

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