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Experimental and Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of Anisaldehyde and Toluene at Different Temperatures
Author(s) -
Ch. Srinivasu,
K. Narendra,
Ch. Kalpana
Publication year - 2010
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2011/701547
Subject(s) - toluene , binary number , intermolecular force , ultrasonic sensor , thermodynamics , materials science , chemistry , physics , organic chemistry , molecule , mathematics , arithmetic , acoustics
Theoretical velocities of binary liquid mixtures of anisaldehyde with toluene at 303.15, 308.15, 313.15 and 318.15 K have been evaluated by using theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Schaff’s collision factor theory and Junjie’s relations. Density and ultrasonic velocity of these mixtures have also been measured as a function of concentration and temperature and the experimental values are compared with the theoretical values. A good agreement has been found between experimental and Nomoto’s theoretical ultrasonic velocities. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures

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