Characterization and Thermal Analysis of Mercury Complexes Containing Intermolecular N→Hg Interactions | Zendy

Hajar Sahebalzamani | Zendy; Farshid Salimi | Zendy; Shahriare Ghammamy | Zendy

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Characterization and Thermal Analysis of Mercury Complexes Containing Intermolecular N→Hg Interactions

Author(s) -

Hajar Sahebalzamani,

Farshid Salimi,

Shahriare Ghammamy

Publication year - 2011

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2011/670931

Subject(s) - thermogravimetry , differential thermal analysis , thermal analysis , raman spectroscopy , chemistry , thermal decomposition , mercury (programming language) , elemental analysis , metal , intermolecular force , coordination complex , analytical chemistry (journal) , thermal , inorganic chemistry , organic chemistry , molecule , thermodynamics , physics , computer science , diffraction , optics , programming language

The new mercury (II) compounds with (L1), (L2) of the general formula [Hg(L)2], have been synthesized and characterized by elemental analysis, electronic and IR, Raman spectra and thermogravimetry and differential thermogravimetry techniques. The changes observed between the spectra of the ligands and of the complexes allowed us to stablish the coordination mode of the metal in complexes and the mechanism of C–H activation is discussed in detail. Thermogravimetry (TG), differential thermal analysis (DTA) and other analytical methods have been applied to the investigation of the thermal behavior and structure of the compounds [Hg(L)2]. Thermal decomposition of these compounds is multi-stage processes

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