Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime | Zendy

Eleni E. Moushi | Zendy; Constantinos G. Efthymiou | Zendy; Spyros P. Perlepes | Zendy; Constantina Papatriantafyllopoulou | Zendy

Open Access

Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime

Author(s) -

Eleni E. Moushi,

Constantinos G. Efthymiou,

Spyros P. Perlepes,

Constantina Papatriantafyllopoulou

Publication year - 2011

Publication title -

international journal of inorganic chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-2026

pISSN - 2090-2034

DOI - 10.1155/2011/606271

Subject(s) - chemistry , oxime , ketone , crystal structure , ring (chemistry) , nickel , crystallography , yield (engineering) , metal , ion , stereochemistry , intermolecular force , cluster (spacecraft) , metal ions in aqueous solution , medicinal chemistry , molecule , organic chemistry , materials science , computer science , programming language , metallurgy

The preparation and crystal structure of a tetranuclear Ni(II) sulfato cluster containing the anion of di-2-pyridyl ketone oxime, (py)2CNO−, are reported. Treatment of NiSO4·6H2O with one equivalent of (py)2CNOH and one equivalent of NEt3 in MeOH leads to the compound [Ni4{(py)2CNO}4(SO4)2(MeOH)4] (1) in moderate yield. The metal ions are linked together by two 3.2111 and two 2.1110 (Harris notation) (py)2CNO− ligands, as well as two 2.1100 SO42− ions to create a rare metallacrown-type (12-MC-4) ring. Strong H-bond intermolecular interactions in 1 lead to the formation of a 1D chain along the axis. Characteristic IR bands are discussed in terms of the known structure of 1

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