Stability Constants of Mixed Ligand Complexes of Transition Metal(II) Ions withN-(2-Hydroxy-1-naphthylidene)-2,6-diisopropylaniline as Primary Ligand and N-(2-Hydroxybenzylidene)-2,3-dimethylaniline as Secondary Ligand
Author(s) -
A.K. Mapari,
Kiran Mangaonkar
Publication year - 2010
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2011/564023
Subject(s) - ternary operation , ligand (biochemistry) , chemistry , stability constants of complexes , dimethylaniline , metal ions in aqueous solution , ion , transition metal , metal , crystallography , medicinal chemistry , inorganic chemistry , receptor , catalysis , organic chemistry , biochemistry , computer science , programming language
Binary and ternary complexes of the type M-Y and M-X-Y [M = Co(II), Ni(II), Cu(II) and Zn(II); X = N-(2-hydroxy-1-naphthylidene)-2,6-diisopropylaniline and Y = N-(2-hydroxybenzylidene)-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and µ = 0.1 M in 75: 25% (v/v) 1,4-dioxne-water medium. The logarithms of the values of stability constants for binary (M-Y) and for ternary (M-X-Y) systems were calculated.
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