Kinetic Studies of Reduction of Tris-(1,1,1,5,5,5-hexafluoroacetylacetonato) ruthenium(III) in Methanol, Ethanol and Propanol | Zendy

Ezekiel Dixon Dikio | Zendy

Open Access

Kinetic Studies of Reduction of Tris-(1,1,1,5,5,5-hexafluoroacetylacetonato) ruthenium(III) in Methanol, Ethanol and Propanol

Author(s) -

Ezekiel Dixon Dikio

Publication year - 2010

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2011/497584

Subject(s) - methanol , ruthenium , chemistry , ethanol , propanol , molar absorptivity , tris , photochemistry , nuclear chemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , physics , optics

The complex tris-(1,1,1,5,5,5-hexafluoroacetylacetonato-) ruthenium(III), hereafter referred to as Ru(hfacac)3, has been synthesized. Ultraviolet and visible spectroscopic measurements of the complex in ethanol revealed three prominent absorption bands at 287, 374 and 525 nm with molar absorptivity coefficients of 4.113, 3.885 and 3.59 respectively. Magnetic susceptibility measurements between 78 and 296 K revealed the complex to assume a low spin configuration of e0 t2g5 and an oxidation state of

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research