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Ion Exchange Properties of Resins Derived fromp-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
Author(s) -
Vinay V. Hiwase,
Ashok B. Kalambe,
K. M. Khedkar,
S. D. Deosarkar
Publication year - 2009
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2010/830484
Subject(s) - resorcinol , formaldehyde , chemistry , ion exchange resin , condensation polymer , nuclear chemistry , monomer , metal ions in aqueous solution , ion exchange , metal , selectivity , catalysis , inorganic chemistry , ion , organic chemistry , polymer
The terpolymeric resins were prepared by base catalyzed polycondensation of p-hydroxybenzaldehyde, resorcinol and formaldehyde. Resin obtained by molar monomer composition, p-hydroxybenzaldehyde: resorcinol: formaldehyde as 1:1:3 was abbreviated as PHBRF-I and that prepared by 1:2:4 composition was abbreviated as PHBRF-II. These resins were characterized by physicochemical methods such as elemental analysis, UV-Vis, IR and NMR. ion- exchange study was carried out with Cu 2+ , Zn 2+ , Ni 2+ , Co 2+ , Pb 2+ & Cd 2+ by batch equilibrium method. The rate of metal ion uptake by PHBRF-II terpolymeric resin was higher than that of PHBRF-I. Effect of pH and electrolytes under specified condition were also studied. The terpolymeric resins show high selectivity for

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