Synthesis of Silver (I) Complexes of Iminoalkyl Functionalised -Heterocyclic Carbenes
Author(s) -
Neil Williams,
Mahboub Merzouk,
Peter B. Hitchcock
Publication year - 2010
Publication title -
international journal of inorganic chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-2026
pISSN - 2090-2034
DOI - 10.1155/2010/628639
Subject(s) - denticity , bromide , yield (engineering) , chemistry , ligand (biochemistry) , single crystal , crystal structure , crystallography , nuclear magnetic resonance spectroscopy , stereochemistry , organic chemistry , materials science , biochemistry , receptor , metallurgy
A range of silver iminoalkyl imidazol-2-ylidene complexes have been isolated in good yield (50%–85%) and characterised by 1H and 13C NMR spectroscopy. A single crystal X-ray diffraction structure determination of 1-{2-(benzylhydrylidene-amino)-ethyl}-3-benzyl imidazol-2-ylidene silver bromide indicated monodentate coordination of the ligand
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