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A new 1-D coordination polymer {[Mn 6 O 2 (O 2 CMe) 10 (H 2 O) 4 ]·2.5H 2 O}  ∞   ( 1 ·2.5H 2 O)  ∞   and the cluster [Mn 6 O 2 (O 2 (O 2 CPh) 10  (py) 2 (MeCN)(H 2 O)]·2MeCN ( 2 ·2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn 3 ( μ   3 -O)(O 2 CR) 6 (L) 2 (L′)] (R = Me, L = L′ = py, ( 1 ·2.5H 2 O)  ∞  ; R = Ph, L = py, L′ = H 2 O,  2 ·2MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [Mn 4   II Mn 2   III ( μ   4 -O) 2 ] 10+  structural core. ( 1 ·2.5H 2 O)  ∞   consists of zigzag chain polymers constructed from [Mn 6 O 2 (O 2 CMe) 10 (H 2 O) 4 ] repeating units linked through acetate ligands, whereas  2 ·2MeCN comprises a discrete Mn 6 -benzoate cluster.

bioinorganic chemistry and applications/bioinorganic chemistry and applications

Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+Unit