Syntheses and Crystal Structures of and | Zendy

Takayoshi Fujii | Zendy; Mihoko Kanno | Zendy; Mitsuo Hirata | Zendy

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Syntheses and Crystal Structures of and

Author(s) -

Takayoshi Fujii,

Mihoko Kanno,

Mitsuo Hirata

Publication year - 2010

Publication title -

international journal of inorganic chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-2026

pISSN - 2090-2034

DOI - 10.1155/2010/326568

Subject(s) - tetrahedron , crystallography , center (category theory) , planar , square (algebra) , crystal structure , terminal (telecommunication) , crystal (programming language) , chemistry , geometry , materials science , engineering , mathematics , computer science , computer graphics (images) , telecommunications , programming language

We have prepared the trinuclear complexes [Cu3{-(NSPh2)2N}2Cl2] (3) and [Cu3{-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions − chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron

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