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Structure of Copper(II) Complexes with 2‐[2‐Hydroxy‐Phenil]‐4,4‐Diphenyl‐1,2‐Dihydro‐4H‐3,1‐Benzoxazine in Chloroform
Author(s) -
S. N. Bolotin,
É. L. Isaeva,
Medina Humaidovna Shamsutdinova,
К. С. Пушкарева,
Н. Н. Буков
Publication year - 2008
Publication title -
advances in physical chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.269
H-Index - 17
eISSN - 1687-7993
pISSN - 1687-7985
DOI - 10.1155/2009/365949
Subject(s) - copper , chloroform , tetragonal crystal system , chemistry , polyhedron , crystallography , bipyramid , ion , crystal structure , stereochemistry , geometry , organic chemistry , mathematics
Electronic spectra of copper(II) complexes CuL2andCu2L2Ac2 (L-2-[2-hydroxy-phenil]-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine, Ac –CH3COO−) (L) in chloroform are studied. Itis shown that complex Cul2 has rhombic bipyramid polyhedron and complex Cu2L2Ac2 has tetragonal pyramidal polyhedron of copper ion. Results of definition of geometry forcomplexes in solution correlate with structure of solid complexes

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