Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals | Zendy

A. Edwin Vasu | Zendy; K. Joseph Santhanaraj | Zendy; Raja Sundararajan | Zendy

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Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals

Author(s) -

A. Edwin Vasu,

K. Joseph Santhanaraj,

Raja Sundararajan

Publication year - 2007

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2008/178560

Subject(s) - benzaldehyde , chemistry , alkyl , yield (engineering) , chlorine , medicinal chemistry , organic chemistry , benzoates , ring (chemistry) , catalysis , materials science , metallurgy

Reactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ring chlorinated alkyl benzoates. A plausible mechanism has been proposed based on the experimental observations and the effect of the alkyl groups on the product yield

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