Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine | Zendy

Basavaraju Bennehalli | Zendy; H. S. Bhojya Naik | Zendy

Open Access

Synthesis and Thermal Degradation Kinetics of Co(II), Ni(II), Cd(II), Zn(II), Pd(II), Rh(III) and Ru(III) Complexes with Methylquinolino[3,2-b]benzodiazepine

Author(s) -

Basavaraju Bennehalli,

H. S. Bhojya Naik

Publication year - 2006

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2007/808902

Subject(s) - thermogravimetric analysis , kinetics , thermal decomposition , chemistry , transition metal , ligand (biochemistry) , degradation (telecommunications) , metal , decomposition , magnetic moment , thermal analysis , inorganic chemistry , nuclear chemistry , thermal , catalysis , organic chemistry , thermodynamics , physics , telecommunications , biochemistry , receptor , quantum mechanics , computer science , condensed matter physics

A series of new complexes formed by the interaction of a new ligand Methylquinolino(3,2-b)benzodiazepine (L) with various transition metal ions have been isolated and characterized by elemental analysis and electronic, IR, magnetic moment and conductivity measurements. Thermogravimetric (TG) studies of the complexes have been performed in order to establish the mode of their thermal degradation. The thermal degradation was found to proceed in two steps. The kinetics and thermodynamic parameters were computed from the thermal decomposition data.

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