Open AccessCobalt and Nickel Complexes Bearing 2,6‐Bis(imino)phenoxy Ligands:Synthesis and Ethylene Oligomerization Study
Author(s) -
JianLong Du,
LiJun Li
Publication year - 2006
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2006/831367
Subject(s) - methylaluminoxane , chemistry , cobalt , nickel , ethylene , catalysis , polymer chemistry , bearing (navigation) , medicinal chemistry , organic chemistry , polymerization , polymer , metallocene , cartography , geography
A series of new cobalt and nickel complexes MLX2 (M = Co or Ni, X = Cl) bearing 2,6-bis(imino)phenoxy ligands have been synthesized. Treatment of the complexes with methylaluminoxane (MAO) leads to active catalysts for ethylene oligomerization. The oligomers are olefins from C4 to C6.
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