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Studies of Binary Complexes of Tripodal Ligandcis,cis-1,3,5-tris(methylamino)cyclohexane with Cr(III) and Fe(III)
Author(s) -
S. Esakki Muthu,
Suban K. Sahoo,
Minati Baral,
B. K. Kanungo
Publication year - 2004
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2005/830389
Subject(s) - cyclohexane , potentiometric titration , tris , aqueous solution , chemistry , ionic strength , ligand (biochemistry) , ionic bonding , stability constants of complexes , medicinal chemistry , ion , inorganic chemistry , stereochemistry , organic chemistry , receptor , biochemistry
The formation of binary complexes of Cr(III) and Fe(III) with a tripodal ligand cis,cis-1,3,5-tris(methylamino)cyclohexane (tmach) (L) has been investigated in solution. The overall stability constants of tmach with Cr(III) and Fe(III) were determined by potentiometric method at an ionic strength of 0.1 M NaClO4 at 25±1°C in aqueous medium. The formation of species like MLH25

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