Studies of Binary Complexes of Tripodal Ligandcis,cis-1,3,5-tris(methylamino)cyclohexane with Cr(III) and Fe(III)
Author(s) -
S. Esakki Muthu,
Suban K. Sahoo,
Minati Baral,
B. K. Kanungo
Publication year - 2004
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2005/830389
Subject(s) - cyclohexane , potentiometric titration , tris , aqueous solution , chemistry , ionic strength , ligand (biochemistry) , ionic bonding , stability constants of complexes , medicinal chemistry , ion , inorganic chemistry , stereochemistry , organic chemistry , receptor , biochemistry
The formation of binary complexes of Cr(III) and Fe(III) with a tripodal ligand cis,cis-1,3,5-tris(methylamino)cyclohexane (tmach) (L) has been investigated in solution. The overall stability constants of tmach with Cr(III) and Fe(III) were determined by potentiometric method at an ionic strength of 0.1 M NaClO4 at 25±1°C in aqueous medium. The formation of species like MLH25
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom