Open AccessUnusual Rearrangement of Dihalocyclopropanes
Author(s) -
Christopher K. Jankowski,
Antoun Bou Laouz,
Denis Lesage,
Eduardo Diaz T.
Publication year - 2003
Publication title -
journal of spectroscopy
Language(s) - English
Resource type - Journals
eISSN - 2314-4920
pISSN - 2314-4939
DOI - 10.1155/2003/209713
Subject(s) - cationic polymerization , reagent , double bond , chemistry , elongation , polymer chemistry , stereochemistry , medicinal chemistry , organic chemistry , materials science , metallurgy , ultimate tensile strength
Dihalocyclopropanation of the double bond of some olefins, leading to dihalocyclopropanes, offered an opportunity to perform their rearrangement to dihalomethylvinyl with Hiyama type reagents, in presence of cationic system such as Cr2
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