Electron ionization mass spectrometry of difurfuryl diamines | Zendy

Alain Lesimple | Zendy; Y. Le Bigot | Zendy; M. Delmas | Zendy; Joseph Banoub | Zendy

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Electron ionization mass spectrometry of difurfuryl diamines

Author(s) -

Alain Lesimple,

Y. Le Bigot,

M. Delmas,

Joseph Banoub

Publication year - 2000

Publication title -

journal of spectroscopy

Language(s) - English

Resource type - Journals

eISSN - 2314-4920

pISSN - 2314-4939

DOI - 10.1155/2000/453723

Subject(s) - mass spectrometry , chemistry , electron ionization , ionization , homolysis , analytical chemistry (journal) , electrospray ionization , heterolysis , ion , fragmentation (computing) , polyatomic ion , chromatography , radical , organic chemistry , computer science , operating system , catalysis

Electron impact mass spectrometry (ei-ms) has aided the structural characterization of a novel series of synthetic difuranic diamines and permitted the comparison with a previous study employing electrospray ionization mass spectrometry. As expected, the molecular radical ion was inexistant in this series of compounds and the fragmentation routes of the molecular radical ion were governed either by homolytic cleavage of the radical R2• or by heterolytic loss of NH3 to give their respective base peaks

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