FTIR and1H-NMR studies of chiral (S)-(-)-2-methylbutyl 4′-(4″-hexyloxy-, (S)-(-)-2-methylbutyl 4′-(4″-(d13)-hexyloxy‒, (S)-(-)-2-methylbutyl 4′-(4″-octyloxy- and (S)-(-)-2-methylbutyl 4′-(4″-(d17)-octyloxyphenyl)benzoates | Zendy

GuanYeow Yeap | Zendy; Yoichi Takanishi | Zendy; Hideo Takezoe | Zendy

Open Access

FTIR and¹H-NMR studies of chiral (S)-(-)-2-methylbutyl 4′-(4″-hexyloxy-, (S)-(-)-2-methylbutyl 4′-(4″-(d₁₃)-hexyloxy‒, (S)-(-)-2-methylbutyl 4′-(4″-octyloxy- and (S)-(-)-2-methylbutyl 4′-(4″-(d₁₇)-octyloxyphenyl)benzoates

Author(s) -

GuanYeow Yeap,

Yoichi Takanishi,

Hideo Takezoe

Publication year - 2000

Publication title -

journal of spectroscopy

Language(s) - English

Resource type - Journals

eISSN - 2314-4920

pISSN - 2314-4939

DOI - 10.1155/2000/207089

Subject(s) - bromide , substituent , chemistry , deuterium , fourier transform infrared spectroscopy , hydroxylation , stereochemistry , organic chemistry , physics , quantum mechanics , enzyme

Four organic chiral compounds (S)-(-)-2-methylbutyl 4′-(4″-hexyloxy-, (S)-(-)-2-methylbutyl 4′-(4″-(d 13 )- hexyloxy-, (S)-(-)-2-methylbutyl 4′-(4″-octyloxy- and (S)-(-)-2-methylbutyl 4′-(4″-(d 17 )-octyloxy-phenyl)benzoates were synthesized via generalized methods and characterized by elemental analysis, FTIR and 1 H NMR. A noticeable difference between the compounds which possess hydrogenated achiral substituent with the deuterated counterparts as exemplified from the FTIR spectra has been suggested for the first time to result from the afinity of the latter compounds towards hydroxylation induced by potassium bromide.

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