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Electronic energy transfer in the    E   (    0  g  +    )   −  D   (    0  u  +    )system of I 2  is investigated in an experiment,where single rovibrational quantum states are prepared, single collision conditionsprevail, and the final states have been determined from dispersed fluorescence. In    I  2  ∗    (  E  )   −  X  ​  ​      (   X=Ar,      N  2   ,      O  2    )the collisional decay is found to be governed by minimumenergy transfer. With    (X=I   2    )    an anomalous behaviour is found for the initiallyprepared E,   ν  =  8  ,   J  =  56   level, which is tentatively ascribed to vibrational excitation ofthe collision partner.

laser chemistry

Collision-Induced <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mtext>E</mml:mtext><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:msubsup><mml:mn>0</mml:mn><mml:mi>g</mml:mi><mml:mo>+</mml:mo></mml:msubsup></mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mo>−</mml:mo><mml:mtext>D</mml:mtext><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:msubsup><mml:mn>0</mml:mn><mml:mi>u</mml:mi><mml:mo>+</mml:mo></mml:msubsup></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:mrow></mml:math> State-…

Collision-Induced E(0g+)−D(0u+) State-…